Paraoxon → 4-Nitrophenol

HRID 254912

Reaction equation

HRID 254912 reaction equation
[CH3:1][CH2:2][O:3][P:4]([O:9][C:10]1[CH:11]=[CH:12][C:13]([N+:16]([O-:18])=[O:17])=[CH:14][CH:15]=1)([O:6][CH2:7][CH3:8])=[O:5]>CO>[P:4]([O:9][CH3:10])([O:6][CH2:7][CH3:8])([O:3][CH2:2][CH3:1])=[O:5].[CH:12]1[C:13]([N+:16]([O-:18])=[O:17])=[CH:14][CH:15]=[C:10]([OH:9])[CH:11]=1

Participants

4

Reactant 1

HCID 9395Paraoxon

Product 2

HCID 9804-NitrophenolHCID 120420Diethyl methyl phosphate

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Paraoxon, when placed in an appropriately buffered methanol solution containing La3+ ions held in a sspH region between 7 and 11, underwent rapid methanolysis at ambient temperature to produce diethyl methyl phosphate and p-nitrophenol. A detailed reaction scheme is given in Scheme 1.

Workup

  1. additioncontaining La3+ ions
  2. customheld in a sspH region between 7 and 11, underwent rapid methanolysis at ambient temperature

Sources & evidence

ORD record
ord-b86319d51abd4abb96b475cbeb2667c0
Source dataset
uspto-grants-2011_01
Patent number
US07875739B2

Linked notes

Loading…