(4-chloro-2-Methylphenoxy)acetic acid → (2,4-Dichlorophenoxy)Acetic Acid

Reaction equation

C[C:2]1[CH:12]=[C:11]([Cl:13])[CH:10]=[CH:9][C:3]=1[O:4][CH2:5][C:6]([OH:8])=[O:7].FC(F)(F)C1C=CC(OC2C=CC(OC(C)C(OCCCC)=O)=CC=2)=NC=1.[Cl:41]C1C=C2C(=CC=1)N=C(OC1C=CC(OC(C)C(OCC)=O)=CC=1)C=N2>>[Cl:41][C:2]1[CH:12]=[C:11]([Cl:13])[CH:10]=[CH:9][C:3]=1[O:4][CH2:5][C:6]([OH:8])=[O:7]

Participants

Reactant 3

HCID 7204(4-chloro-2-Methylphenoxy)acetic acid

HCID 50897Fluazifop-butyl

HCID 53518Quizalofop-ethyl

Product 1

HCID 1486(2,4-Dichlorophenoxy)Acetic Acid

Procedure

2-methyl-4-chlorophenoxyacetic acid; butyl 2-[4-(5-trifluoromethyl-2-pyridyloxy)phenoxy]propionate (including esters and salts thereof); ethyl 2-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]propionate; etc.

Sources & evidence

ORD record: ord-5b21513a125948329fe11dbc04aa1daf
Source dataset: uspto-grants-1987_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04698094

Reaction notes

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