Dimethyldithiocarbamic acid, dimethylamine → alpha-(1-Nitroethyl)benzyl dimethyldithiocarbamate

HRID 259455

Reaction equation

HRID 259455 reaction equation
[N+:1]([C:4](=[CH2:12])[CH2:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)([O-:3])=[O:2].[CH3:13][N:14]([CH3:18])[C:15](=[S:17])[S-:16].C[NH2+]C>C(=S)=S>[CH3:13][N:14]([CH3:18])[C:15](=[S:16])[S:17][CH:5]([CH:4]([N+:1]([O-:3])=[O:2])[CH3:12])[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1

Participants

4

Reactant 2

HCID 11728Dimethyldithiocarbamic acid, dimethylamineHCID 575754(2-Nitro-2-propenyl)benzene

Product 1

HCID 21324624alpha-(1-Nitroethyl)benzyl dimethyldithiocarbamate

Reagents, catalysts & solvents 1

HCID 6348Carbon DisulfideSolvent

Procedure

As in Example 17, reaction of (2-nitro-2-propenyl)benzene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide, gave α-(1-nitroethyl)benzyl dimethyldithiocarbamate melting at 92° - 94° C. when recrystallized without heating from acetone-ethanol solution.

Sources & evidence

ORD record
ord-83508ec820114cfea6cbbdc5808ab3b7
Source dataset
uspto-grants-1977_07
Patent number
US04038288

Linked notes

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