Dimethyldithiocarbamic acid, dimethylamine → 4-Acetoxy-alpha-(nitromethyl)benzyl dimethyldithiocarbamate
Reaction equation
[C:1]([O:4][C:5]1[CH:15]=[CH:14][C:8]([CH:9]=[CH:10][N+:11]([O-:13])=[O:12])=[CH:7][CH:6]=1)(=[O:3])[CH3:2].[CH3:16][N:17]([CH3:21])[C:18](=[S:20])[S-:19].C[NH2+]C>C(=S)=S>[CH3:16][N:17]([CH3:21])[C:18](=[S:19])[S:20][CH:9]([CH2:10][N+:11]([O-:13])=[O:12])[C:8]1[CH:14]=[CH:15][C:5]([O:4][C:1](=[O:3])[CH3:2])=[CH:6][CH:7]=1Participants
4
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Procedure
As in Example 17, reaction of 4-acetoxy-β-nitrostyrene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave 4-acetoxy-α-(nitromethyl)benzyl dimethyldithiocarbamate melting at 116° - 118° C. after recrystallization without heating from acetone-methanol solution.