Dimethyldithiocarbamic acid, dimethylamine → 3,4-(Methylenedioxy)-alpha-(nitromethyl)benzyl dimethyldithiocarbamate

HRID 26149

Reaction equation

HRID 26149 reaction equation
[CH2:1]1[O:14][C:13]2[CH:12]=[CH:11][C:5]([CH:6]=[CH:7][N+:8]([O-:10])=[O:9])=[CH:4][C:3]=2[O:2]1.[CH3:15][N:16]([CH3:20])[C:17](=[S:19])[S-:18].C[NH2+]C>C(=S)=S>[CH3:15][N:16]([CH3:20])[C:17](=[S:18])[S:19][CH:6]([CH2:7][N+:8]([O-:10])=[O:9])[C:5]1[CH:11]=[CH:12][C:13]2[O:14][CH2:1][O:2][C:3]=2[CH:4]=1

Participants

4

Reactant 2

HCID 11728Dimethyldithiocarbamic acid, dimethylamineHCID 949455-(2-Nitroethenyl)-1,3-benzodioxole

Product 1

HCID 213246273,4-(Methylenedioxy)-alpha-(nitromethyl)benzyl dimethyldithiocarbamate

Reagents, catalysts & solvents 1

HCID 6348Carbon DisulfideSolvent

Procedure

As in Example 17, reaction of 3,4-(methylenedioxy)-β-nitrostyrene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave 3,4-(methylenedioxy)-α-(nitromethyl)benzyl dimethyldithiocarbamate melting at 122° C.-124° C. when recrystallized without heating from acetone-ethanol solution.

Sources & evidence

ORD record
ord-c2556666c56a4f38a98f08ccb528d279
Source dataset
uspto-grants-1979_04
Patent number
US04148795

Linked notes

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