Ammonia → N-methyldihydrophenethylamine

HRID 26264

Reaction equation

HRID 26264 reaction equation
[CH3:1][NH:2][CH2:3][CH2:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.[Li].N>C(O)C>[CH3:1][NH:2][CH2:3][CH2:4][CH:5]1[CH:6]=[CH:7][CH:8]=[CH:9][CH2:10]1

Participants

5

Reactant 3

HCID 222AmmoniaHCID 11503N-MethylbenzeneethanamineHCID 3028194Lithium

Product 1

HCID 21325368N-methyldihydrophenethylamine

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

46 g. (0.34 moles) of N-methylphenethylamine are reduced by treatment with 16 g. of lithium (2.3 g. atom) in 1.5 l. of ammonia and 250 ml. ethanol according to the procedure of Example 1(a) to yield crude N-methyldihydrophenethylamine.

Sources & evidence

ORD record
ord-62363256f8234758ae7a253104fc17bb
Source dataset
uspto-grants-1979_04
Patent number
US04149001

Linked notes

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