Nitrobenzene → 1,7-Dinitroanthraquinone

HRID 262964

Reaction equation

[N+:1]([C:4]1[CH:17]=[CH:16][C:15]2[C:14](=[O:18])C3C(=CC=CC=3)[C:7](=[O:19])[C:6]=2[C:5]=1[N+]([O-])=O)([O-:3])=[O:2].[N+:23]([C:26]1[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=1)([O-:25])=[O:24]>>[N+:23]([C:26]1[C:31]2[C:7](=[O:19])[C:6]3[C:15](=[CH:16][CH:17]=[C:4]([N+:1]([O-:3])=[O:2])[CH:5]=3)[C:14](=[O:18])[C:30]=2[CH:29]=[CH:28][CH:27]=1)([O-:25])=[O:24]

Participants

Reactant 2

HCID 7416Nitrobenzene

HCID 425969,10-Anthracenedione, 1,2-dinitro-

Product 1

HCID 741471,7-Dinitroanthraquinone

Procedure

100 g of a dinitroanthraquinone mixture of the composition A are employed and are stirred with C ml of nitrobenzene at D° C. for B hours, the precipitate is filtered off at D° C. and washed with 50 ml of nitrobenzene and the material on the filter is freed from nitrobenzene in vacuo. E g of 1,7-dinitro-anthraquinone of the composition F are obtained.

Workup

filtrationfor B hours, the precipitate is filtered off at D° C
washand washed with 50 ml of nitrobenzene

Sources & evidence

ORD record: ord-f4a79c98b0d146c1877b4b11d58141ec
Source dataset: uspto-grants-1979_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04155921

Linked notes

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