Phenanthridine → Potassium phenanthridine

HRID 2638

Reaction equation

HRID 2638 reaction equation
[CH:1]1[C:14]2[C:5](=[N:6][CH:7]=[C:8]3[C:13]=2[CH:12]=[CH:11][CH:10]=[CH:9]3)[CH:4]=[CH:3][CH:2]=1.[K:15]>C(COC)OC>[CH:1]1[C:14]2[C:5](=[N:6][CH:7]=[C:8]3[C:13]=2[CH:12]=[CH:11][CH:10]=[CH:9]3)[CH:4]=[CH:3][CH:2]=1.[K:15]

Participants

4

Reactant 2

HCID 9189PhenanthridineHCID 5462222Potassium

Product 1

HCID 67604644Potassium phenanthridine

Reagents, catalysts & solvents 1

HCID 80711,2-DimethoxyethaneSolvent

Procedure

A potassium phenanthridine (radical-anion complex) solution is prepared by adding about 3.5 g phenanthridine and about 0.75 g potassium metal to about 20 ml of monoglyme yielding a red-colored product. A sample of PTFE, PFA and RO2800 each immersed for 3 minutes in this bath show surface discoloration indicative of chemical modification as discussed hereinabove.

Sources & evidence

ORD record
ord-6f9862849edd4f0d80d4a6085f88fd8d
Source dataset
uspto-grants-1998_03
Patent number
US05730890

Linked notes

Loading…