HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Nitrobenzyl chloride → 4-Nitrobenzyltriphenylphosphonium chloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Nitrobenzyl chloride | HCID 7482 | — |
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Product | 4-Nitrobenzyltriphenylphosphonium chloride | HCID 12000315 | — |
Reaction Steps
A solution of 26.3 g (0.10 moles) of triphenylphosphide and 17.2 g (0.10 moles) of p-nitrobenzyl chloride in 50 ml of benezene is refluxed for 2 hours. After cooling the solid is collected and washed with benzene. Crystallization from carbon tetrachloride petroleum ether gives colorless crystals, m.p. 278°-280° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04150105 |
| Source dataset | uspto-grants-1979_04 |
| ORD ID | ord-6e5bd4e07c044528b4ceaa1ba598509a |
| Source note | uspto-grants-1979_04 |