1-Bromo-2-methylbutane, (+)- → HCID 178418364, compound

HRID 2648

Reaction equation

HRID 2648 reaction equation
Br[CH2:2][C@@H:3]([CH3:6])[CH2:4][CH3:5].FC(F)(F)S(O[C:13]1[C:18]([F:19])=[CH:17][C:16]([CH:20]2[CH2:25][CH2:24][Si:23](CCCCC)([C:26]3C=[CH:30][CH:29]=[CH:28][CH:27]=3)[CH2:22][CH2:21]2)=[CH:15][C:14]=1[F:37])(=O)=O>>[CH2:26]([Si@H:23]1[CH2:24][CH2:25][C@H:20]([C:16]2[CH:17]=[C:18]([F:19])[C:13]([CH2:2][C@@H:3]([CH3:6])[CH2:4][CH3:5])=[C:14]([F:37])[CH:15]=2)[CH2:21][CH2:22]1)[CH2:27][CH2:28][CH2:29][CH3:30]

Participants

3

Reactant 2

HCID 54641671-Bromo-2-methylbutane, (+)-HCID 23364888(2,6-Difluoro-4-(4-n-pentyl-4-phenyl-4-silacyclohexyl)phenyl) trifluoromethanesulfonate

Product 1

HCID 178418364HCID 178418364, compound

Procedure

The general procedure of Example 18 was repeated using (S)-1-bromo-2-methylbutane and (2,6-difluoro-4-(4-n-pentyl-4-phenyl-4-silacyclohexyl)phenyl) trifluoromethanesulfonate, thereby obtaining the intended compound.

Workup

  1. customobtaining the intended compound

Sources & evidence

ORD record
ord-88bba747b04c4ea0a87b10994af1c1f6
Source dataset
uspto-grants-1998_03
Patent number
US05730902

Linked notes

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