Diethyl Ether → Lithium tetrakis(pentafluorophenyl)borate

HRID 265596

Reaction equation

HRID 265596 reaction equation
[F:1][C:2]1[C:7]([B:8]([C:20]2[C:25]([F:26])=[C:24]([F:27])[C:23]([F:28])=[C:22]([F:29])[C:21]=2[F:30])[C:9]2[C:14]([F:15])=[C:13]([F:16])[C:12]([F:17])=[C:11]([F:18])[C:10]=2[F:19])=[C:6]([F:31])[C:5]([F:32])=[C:4]([F:33])[C:3]=1[F:34].CCOCC.[F:40][C:41]1[C:46]([Li:47])=[C:45]([F:48])[C:44]([F:49])=[C:43]([F:50])[C:42]=1[F:51]>CCCCCC>[F:26][C:25]1[C:20]([B-:8]([C:46]2[C:45]([F:48])=[C:44]([F:49])[C:43]([F:50])=[C:42]([F:51])[C:41]=2[F:40])([C:7]2[C:2]([F:1])=[C:3]([F:34])[C:4]([F:33])=[C:5]([F:32])[C:6]=2[F:31])[C:9]2[C:10]([F:19])=[C:11]([F:18])[C:12]([F:17])=[C:13]([F:16])[C:14]=2[F:15])=[C:21]([F:30])[C:22]([F:29])=[C:23]([F:28])[C:24]=1[F:27].[Li+:47]

Participants

5

Reactant 3

HCID 3283Diethyl EtherHCID 582056Tris(pentafluorophenyl)boraneHCID 178419089HCID 178419089, compound

Product 1

HCID 23709652Lithium tetrakis(pentafluorophenyl)borate

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

The obtained tris(pentafluorophenyl)boron (41 mmol) was reacted with an ether solution of pentafluorophenyllithium (41 mmol) in hexane, to isolate lithium tetrakis(pentafluorophenyl)borate as a white solid product.

Sources & evidence

ORD record
ord-ad714882e1fd4777b61373ff94cd6e4c
Source dataset
uspto-grants-1997_07
Patent number
US05648443

Linked notes

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