HCID 21556903, compound → 5-Nitro-2-hexanone
Reaction equation
[N+]([CH2:4][C:5](C)([OH:13])[CH2:6][CH2:7][CH:8]([N+:10]([O-:12])=[O:11])[CH3:9])([O-])=O>C1C=CC=CC=1>[N+:10]([CH:8]([CH3:9])[CH2:7][CH2:6][C:5](=[O:13])[CH3:4])([O-:12])=[O:11]Participants
3
Reagents, catalysts & solvents 1
Procedure
To a solution of 0.91 gram of 1,5-dinitro-2-methyl-2-hexanol in 25 milliliters of benzene there was added 4.2 grams of alumina. The mixture was stirred for 24 hours, and the alumina was removed by filtration. After evaporation of the filtrate there was obtained 0.29 gram of 5-nitro-2-hexanone which was identified by infrared and proton magnetic resonance.
Workup
- customthe alumina was removed by filtration
- customAfter evaporation of the filtrate there
Sources & evidence
- ORD record
- ord-a1ec2d07712f4be1ad68c7b6ff1c2dd1
- Source dataset
- uspto-grants-1976_03
- Patent number
- US03941846
Reaction notes
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