Butanal → Butanal

HRID 268194

Reaction equation

HRID 268194 reaction equation
N[C:2]1([O:8]O)[CH2:7][CH2:6][CH2:5][CH2:4][CH2:3]1.[CH:10](=[O:14])[CH2:11][CH2:12][CH3:13].C(O)(=O)C.N>CO>[C:2]1(=[O:8])[CH2:7][CH2:6][CH2:5][CH2:4][CH2:3]1.[CH:10](=[O:14])[CH2:11][CH2:12][CH3:13]

Participants

6

Reactant 3

HCID 261ButanalHCID 12432Ammonia acetateHCID 193800581-Aminocyclohexyl hydroperoxide

Product 2

HCID 261ButanalHCID 7967Cyclohexanone

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

1-Aminocyclohexyl hydroperoxide (13.1 g.), butyraldehyde (7.2 g.), methanol (25 cc.) and ammonia acetate (1.0 g.) were mixed and stored at 0°C overnight. Working up as in Example 39 gave cyclohexanone and butyraldehyde, and a product (8.4 g.), b.p. 89°/0.3 mm. (peroxide equivalent, 204; pechloric acid equivalent, 206; which was identified as ##SPC37##

Sources & evidence

ORD record
ord-d71560725e124bf9937c2ce881b6cce1
Source dataset
uspto-grants-1976_03
Patent number
US03947406

Linked notes

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