2-p-Anisoyloxypyridine → Pyridin-2-yl benzoate

HRID 268511

Reaction equation

[N+]([C:4]1[CH:5]=[C:6]([CH:16]=[C:17]([N+]([O-])=O)[CH:18]=1)[C:7]([O:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][N:11]=1)=[O:8])([O-])=O.C1(C)C=C(C)C=C(C)C=1C(OC1C=CC=CN=1)=O.C(OC1C=CC=CN=1)(=O)C(C)(C)C.C(OC1C=CC=CN=1)(=O)C1C=CC(OC)=CC=1>>[C:7]([O:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][N:11]=1)(=[O:8])[C:6]1[CH:5]=[CH:4][CH:18]=[CH:17][CH:16]=1

Participants

Reactant 4

HCID 125571162-p-Anisoyloxypyridine

HCID 13140422Pyridin-2-yl 2,2-dimethylpropanoate

HCID 131404232-Mesitoyloxypyridine

HCID 214389492-(3,5-Dinitrobenzoyloxy)pyridine

Product 1

HCID 817610Pyridin-2-yl benzoate

Procedure

Other products prepared by this procedure are 2-(3,5-dinitrobenzoyloxy)pyridine (88%), 2-mesitoyloxypyridine (86%), 2-pivaloyloxypyridine (93%), and 2-p-anisoyloxypyridine (100%).

Workup

customOther products prepared by this procedure

Sources & evidence

ORD record: ord-0db1ee4c89d9403abc2fd0514d9792fd
Source dataset: uspto-grants-1976_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US03947488

Linked notes

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