2'-Bromobiphenyl-3-carboxylic acid ethyl ester → Ethyl 2'-bromo-2-biphenylcarboxylate

HRID 269548

Reaction equation

HRID 269548 reaction equation
C(OC([C:6]1[CH:7]=[C:8]([C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=2[Br:18])[CH:9]=[CH:10][CH:11]=1)=O)C.[CH2:19]([O:21][C:22](C1C=CC=CC=1OB(C1C=CC=CC=1)O)=[O:23])[CH3:20]>>[CH2:19]([O:21][C:22]([C:7]1[C:8]([C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=2[Br:18])=[CH:9][CH:10]=[CH:11][CH:6]=1)=[O:23])[CH3:20]

Participants

3

Reactant 2

HCID 587309812'-Bromobiphenyl-3-carboxylic acid ethyl esterHCID 693149282-Ethoxycarbonylphenylphenyl boronic acid

Product 1

HCID 69309506Ethyl 2'-bromo-2-biphenylcarboxylate

Procedure

Prepared using the same conditions for the synthesis of 2′-bromo-biphenyl-3-carboxylic acid ethyl ester substituting 3-ethoxycarbonylphenyl boronic acid with 2-ethoxycarbonylphenylphenyl boronic acid.

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-ebdae8c163094a05b25c000105231374
Source dataset
uspto-grants-2008_11
Patent number
US07446222B2

Linked notes

Loading…