Phenylsulfonyl ketenethioacetal → HCID 178503876, compound

HRID 27386

Reaction equation

[C:1]1([S:7]([C:10]([C:16]#[N:17])=[C:11]([S:14][CH3:15])SC)(=[O:9])=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH3:18][C:19]1[N:20]=[CH:21][NH:22][C:23]=1[CH2:24][S:25][CH2:26][CH2:27][NH2:28]>>[C:1]1([S:7]([C:10]([C:16]#[N:17])=[C:11]([S:14][CH3:15])[NH:28][CH2:27][CH2:26][S:25][CH2:24][C:23]2[NH:22][CH:21]=[N:20][C:19]=2[CH3:18])(=[O:8])=[O:9])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

Reactant 2

HCID 194051Phenylsulfonyl ketenethioacetal

HCID 178433288HCID 178433288, compound

Product 1

HCID 178503876HCID 178503876, compound

Procedure

Equimolar amounts of 1-benzenesulfonyl-1-cyano-2,2-bis(methylthio)ethylene [prepared according to the procedure described by M. Augustin et al., Z. Chem., 17, 289 (1977)] and 2-[(4-methyl-1H-imidazol-5-yl)methylthio]ethylamine [prepared according to the procedure described in U.S. Pat. No. 3,950,353] are reacted according to the general procedure of Example 6A, and the title product is produced.

Workup

custom3,950,353] are reacted

Sources & evidence

ORD record: ord-159cb7efc2f84e90b3701ceb6e2e89f7
Source dataset: uspto-grants-1980_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04221737

Linked notes

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