Propylethinylcarbinol → 1-(3-Hydroxyhex-1-yn-1-yl)-2,2,6-trimethylcyclohexan-1-ol

HRID 280423

Reaction equation

[CH:1]#[C:2][CH:3]([OH:7])[CH2:4][CH2:5][CH3:6].[CH3:8][CH:9]1[CH2:14][CH2:13][CH2:12][C:11]([CH3:16])([CH3:15])[C:10]1=[O:17]>>[OH:17][C:10]1([C:1]#[C:2][CH:3]([OH:7])[CH2:4][CH2:5][CH3:6])[C:11]([CH3:16])([CH3:15])[CH2:12][CH2:13][CH2:14][CH:9]1[CH3:8]

Participants

Reactant 2

HCID 7746Propylethinylcarbinol

HCID 170002,2,6-Trimethylcyclohexanone

Product 1

HCID 202260351-(3-Hydroxyhex-1-yn-1-yl)-2,2,6-trimethylcyclohexan-1-ol

Procedure

the addition of hex-1-yn-3-ol to 2,6,6-trimethylcyclohexanone to give 1-(1-hydroxy-2,6,6-trimethylcyclohexyl)-hex-1-yn-3-ol;

Sources & evidence

ORD record: ord-9c8e43c6c61b46e4963151b6f457214e
Source dataset: uspto-grants-1986_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04588849

Linked notes

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