Methyl chloroformate → Phosphinecarboxylic acid, dibutoxy-, methyl ester, oxide

HRID 280867

Reaction equation

C([O:5][P:6]([O:12][CH2:13][CH2:14][CH2:15][CH3:16])[O:7][CH2:8][CH2:9][CH2:10][CH3:11])CCC.Cl[C:18]([O:20][CH3:21])=[O:19]>>[CH3:21][O:20][C:18]([P:6](=[O:5])([O:7][CH2:8][CH2:9][CH2:10][CH3:11])[O:12][CH2:13][CH2:14][CH2:15][CH3:16])=[O:19]

Participants

Reactant 2

HCID 6586Methyl chloroformate

HCID 7623Tributyl phosphite

Product 1

HCID 512112Phosphinecarboxylic acid, dibutoxy-, methyl ester, oxide

Procedure

From 26.6 g (0.10 mole) of tri-n-butylphosphite and 18.9 g (0.20 mole) of methyl chloroformate (80° C., 6 hours).

Sources & evidence

ORD record: ord-8be428704e41409e8ce50e804f42616f
Source dataset: uspto-grants-1986_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04591583

Linked notes

Loading…