3-Iodo-4-methylbenzyl alcohol → 3-Iodo-4-methylbenzaldehyde

HRID 2973

Reaction equation

HRID 2973 reaction equation
[I:1][C:2]1[CH:3]=[C:4]([CH:7]=[CH:8][C:9]=1[CH3:10])[CH2:5][OH:6]>C(Cl)Cl.O=[Mn]=O>[I:1][C:2]1[CH:3]=[C:4]([CH:7]=[CH:8][C:9]=1[CH3:10])[CH:5]=[O:6]

Participants

4

Reactant 1

HCID 51667983-Iodo-4-methylbenzyl alcohol

Product 1

HCID 123302543-Iodo-4-methylbenzaldehyde

Reagents, catalysts & solvents 2

HCID 14801Manganese dioxideCatalystHCID 6344DichloromethaneSolvent

Procedure

A mixture of 1.0 mmol of this alcohol and 5.0 mmol of MnO2 in 5 mL of CH2Cl2 was stirred for 16 h at rt. Chromatography provided 3-iodo-4-methylbenzaldehyde.

Sources & evidence

ORD record
ord-bd82a5043a4441d6bb653b1731c79827
Source dataset
uspto-grants-1998_03
Patent number
US05731432

Linked notes

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