HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2979Generated: October 25, 2026
Allyltributylstannane → n-Trimethylsilylethoxymethyl-5-(3'-allyl-4'-methylphenyl)tetrazole
https://huagongshe.com/reaction/2979
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Allyltributylstannane | HCID 90628 | — |
| Reactant | 2-Chloromethyl 2-(trimethylsilyl)ethyl ether | HCID 2724271 | — |
| Reactant | 5-(3-Bromo-4-methylphenyl)-2H-tetrazole | HCID 178418249 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | n-Trimethylsilylethoxymethyl-5-(3'-allyl-4'-methylphenyl)tetrazole | HCID 69840625 | — |
Reaction Steps
A solution of 1.0 mmol of this tetrazole, 2.0 mmol of SEMCl in 10 mL DMF was stirred for 1 h. 2.0 mmol of allyltributyltin and 0.1 mmol of Pd(Ph3)4 was added and heated at 70° C. for 14 h. Chromatography provided N-trimethylsilylethoxymethyl-5-(3'-allyl-4'-methylphenyl)tetrazole.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US05731432 |
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| Source dataset | uspto-grants-1998_03 |
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| ORD ID | ord-23c1255e56f24480bb48d53be97ec0f6 |
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| Source note | uspto-grants-1998_03 |
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