Sodium;3-phenylprop-2-enoate → Europium(3+);tris(3-phenylprop-2-enoate)

HRID 325837

Reaction equation

HRID 325837 reaction equation
[Cl-].[Eu+3:2].[Cl-].[Cl-].[C:5]([O-:15])(=[O:14])[CH:6]=[CH:7][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1.[Na+]>O>[C:5]([O-:15])(=[O:14])[CH:6]=[CH:7][C:8]1[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1.[Eu+3:2].[C:5]([O-:15])(=[O:14])[CH:6]=[CH:7][C:8]1[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1.[C:5]([O-:15])(=[O:14])[CH:6]=[CH:7][C:8]1[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1

Participants

4

Reactant 2

HCID 517350Sodium;3-phenylprop-2-enoateHCID 9859933Europium chloride, anhydrous 99.9%

Product 1

HCID 86739358Europium(3+);tris(3-phenylprop-2-enoate)

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

In 300 ml of purified water, 1.64 g of sodium hydroxide was dissolved. In the resultant aqueous solution, 6.06 g of cinnamic acid (purity 99.9%, conjugate number 4) was thoroughly dissolved under stirring, to produce a sodium cinnamate aqueous solution. The pH value of this aqueous solution was adjusted to 11.0 with a 0.1 N sodium hydroxide aqueous solution. Then, a europium chloride aqueous solution obtained in advance by thoroughly dissolving 5.0 g of europium chloride (EuCl3.6H2O; purity 99.99%) in 100 ml of purified water was gradually added with stirring into the aforementioned sodium cinnamate aqueous solution at room temperature. Consequently, a white salt of europium cinnamate, [(C6H5CH=CHCOO)3Eu], was obtained in the form of a precipitate. Subsequently, the reaction solution was adjusted to pH 5.0 with 0.1 N hydrochloric acid and then thoroughly stirred. The europium cinnamate thus produced was separated by means of a glass filter, thoroughly washed with 500 ml of purified water and dried in vacuo at 80° to 100° C. for 20 to 24 hours.

Workup

  1. additionwas gradually added

Sources & evidence

ORD record
ord-29f8b9a9def543a5b1f53387b2ef8931
Source dataset
uspto-grants-1984_04
Patent number
US04443380

Linked notes

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