HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethylene → 1-(2-Bromoethyl)-3,5-dimethyl Adamantane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethylene | HCID 6325 | — |
| Reactant | 1-Bromo-3,5-dimethyladamantane | HCID 98317 | — |
| Reactant | Bromhydrol | HCID 166749 | — |
| Solvent | Hexane | HCID 8058 | — |
| Product | 1-(2-Bromoethyl)-3,5-dimethyl Adamantane | HCID 15068767 | 48% |
Reaction Steps
Mix 1.4 mol of 1-bromo-3,5-dimethyl adamantane (I) in hexane with 0.6 mol of aluminum bromide at -75° C. Subsequently, pass ethylene through the solution for 20-30 minutes, stir for 5 min., and pour the reaction mixture onto ice water. Extract with ether, dry the organic phase and evaporate to dryness. Recrystallize the residue from methanol. (Yield: 48%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05061703 |
| Source dataset | uspto-grants-1991_10 |
| ORD ID | ord-8ea37ed7204243fe814166548c4d8d15 |
| Source note | uspto-grants-1991_10 |