Sulfuric Acid → HCID 178512812, compound
Reaction equation
[NH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][NH2:8].CS[C:11](=[NH:13])[NH2:12].OS(O)(=O)=O>O>[NH:1]([CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][NH2:8])[C:11]([NH2:13])=[NH:12]Participants
5
Reactant 3
Product 1
Reagents, catalysts & solvents 1
Procedure
To 2.3 g. of 1,6-diaminohexane dissolved in 50 ml. of H2O was added dropwise with vigorous stirring a solution of 2 g. of S-methylthiopseudourea.H2SO4 in 20 ml. of H2O. After the completion of addition, the stirring was continued for 15 hours, after which the precipitate (the diadduct) was filtered. The filtrate was concentrated to a viscous oil which upon the addition of 50 ml. of MeOH precipitated 718 mg. of white powder.
Workup
- additionAfter the completion of addition
- filtrationafter which the precipitate (the diadduct) was filtered
- concentrationThe filtrate was concentrated to a viscous oil which upon the addition of 50 ml
- customof MeOH precipitated 718 mg
Sources & evidence
- ORD record
- ord-9cf58c54b4b744f8a9806c38daf1df95
- Source dataset
- uspto-grants-1988_08
- Patent number
- US04762949
Reaction notes
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