Fluorine → 3,3,3-Trifluoro-2-(trifluoromethyl)-1-propene

HRID 35384

Reaction equation

FF.[F:3][C:4]([F:16])([F:15])[CH:5]([C:11]([F:14])([F:13])[F:12])[C:6](OCCl)=O>>[F:3][C:4]([F:16])([F:15])[C:5]([C:11]([F:14])([F:13])[F:12])=[CH2:6]

Participants

Reactant 2

HCID 24524Fluorine

HCID 13954659Monochloromethyl 2-trifluoromethyl-3,3,3-trifluoropropanoate

Product 1

HCID 914503,3,3-Trifluoro-2-(trifluoromethyl)-1-propene

Procedure

Among the thus produced fluorine-containing compounds (I), monochloromethyl 2-trifluoromethyl-3,3,3-trifluoropropanoate is reacted with an amine to give 2-trifluoromethyl-3,3,3-trifluoropropene in a high yield.

Sources & evidence

ORD record: ord-662c89e71cd04d96ae7e29b5fd347433
Source dataset: uspto-grants-1988_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04766238

Linked notes

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