2,2,3,3-Tetramethylcyclopropane-1-carbonyl chloride → HCID 20508315, compound
Reaction equation
[C:1]([C:3]1[C:4]([CH3:12])=[C:5]([CH2:10][OH:11])[C:6]([CH3:9])=[CH:7][CH:8]=1)#[N:2].[CH3:13][C:14]1([CH3:22])[C:16]([CH3:18])([CH3:17])[CH:15]1[C:19](Cl)=[O:20]>>[CH3:13][C:14]1([CH3:22])[C:16]([CH3:18])([CH3:17])[CH:15]1[C:19]([O:11][CH2:10][C:5]1[C:6]([CH3:9])=[CH:7][CH:8]=[C:3]([C:1]#[N:2])[C:4]=1[CH3:12])=[O:20]Participants
3
Procedure
In a similar manner, (3-cyano-2,6-dimethylphenyl)methanol is reacted with other 3-(2-halo-3,3,3-trifluoropropenyl)-2,2-dimethylcyclopropanecarboxylic acid chlorides and others 3-(2,2-dihaloethenyl)-2,2-dimethylcyclopropanecarboxylic acid chlorides, or 2,2,3,3-tetramethylcyclopropanecarboxylic acid chloride to give other (3-cyano-2,6-dimethylphenyl)methyl 3-(2-halo-3,3,3-trifluoropropenyl)-2,2-dimethylcyclopropanecarboxylates and 3-(2,2-dihaloethenyl)-2,2-dimethylcyclopropanecarboxylates within the scope of this invention, or (3-cyano-2,6-dimethylphenyl)methyl 2,2,3,3-tetramethylcyclopropanecarboxylate, respectively.
Sources & evidence
- ORD record
- ord-ce56156838ac45cbb542b1930364595f