5-Phenyl-2-pyridinamine → 1,1'-(1,12-dodecanediyl)bis(5-phenyl-2(1H)-pyridinimine) dihydrobromide

HRID 355943Notes

Reaction equation

HRID 355943 reaction equation
[Br:1][CH:2](Br)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13].[NH2:15][C:16]1[CH:21]=[CH:20][C:19]([C:22]2[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=2)=[CH:18][N:17]=1>>[BrH:1].[BrH:1].[CH2:2]([N:17]1[CH:18]=[C:19]([C:22]2[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=2)[CH:20]=[CH:21][C:16]1=[NH:15])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][N:17]1[CH:18]=[C:19]([C:22]2[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=2)[CH:20]=[CH:21][C:16]1=[NH:15]

Participants

3

Reactant 2

HCID 1050975-Phenyl-2-pyridinamineHCID 113249061,1-Dibromododecane

Product 1

HCID 676452791,1'-(1,12-dodecanediyl)bis(5-phenyl-2(1H)-pyridinimine) dihydrobromide

Procedure

The procedure is as before, with dibromododecane and 2-amino-5-phenylpyridine. The product obtained is purified by recrystallization in methanol. Its m.p.=185° C.

Workup

  1. customThe product obtained
  2. customis purified by recrystallization in methanol

Sources & evidence

ORD record
ord-78f5ec2787d6472997528e93e764da4c
Source dataset
uspto-grants-1998_11
Patent number
US05834491

Reaction notes

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