4-Octylaniline → N-(p-octylphenyl)-2,4,6-triphenylpyridinium triflate

HRID 359305

Reaction equation

HRID 359305 reaction equation
[O-:1][S:2]([C:5]([F:8])([F:7])[F:6])(=[O:4])=[O:3].[C:9]1([C:15]2[CH:20]=[C:19]([C:21]3[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=3)[CH:18]=[C:17]([C:27]3[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=3)[O+]=2)[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.[CH2:33]([C:41]1[CH:47]=[CH:46][C:44]([NH2:45])=[CH:43][CH:42]=1)[CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH3:40]>C(O)C>[O-:4][S:2]([C:5]([F:8])([F:7])[F:6])(=[O:3])=[O:1].[CH2:33]([C:41]1[CH:42]=[CH:43][C:44]([N+:45]2[C:15]([C:9]3[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=3)=[CH:20][C:19]([C:21]3[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=3)=[CH:18][C:17]=2[C:27]2[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=2)=[CH:46][CH:47]=1)[CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH3:40]

Participants

4

Reactant 2

HCID 853464-OctylanilineHCID 2778031AG-G-77560

Product 1

HCID 20064818N-(p-octylphenyl)-2,4,6-triphenylpyridinium triflate

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

A 4.58-g portion (0.01 mole) of 2,4,6-triphenylpyrylium triflate is added to 200 ml of ethanol. To this solution, 2.05 g (0.01 mole) of p-n-octylaniline is added. The mixture is refluxed for about 20 hours. Upon removing the ethanol by rotating evaporation, an orange oil remains. To remove the last of the ethanol the oil is placed under high vacuum.

Workup

  1. temperatureThe mixture is refluxed for about 20 hours
  2. customUpon removing the ethanol
  3. customevaporation
  4. customTo remove the last of the ethanol the oil

Sources & evidence

ORD record
ord-7852d11320734bafb0ba94ae0caa2fb1
Source dataset
uspto-grants-1991_03
Patent number
US05000873

Linked notes

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