HuagongsheHuagongshe Chemistry Print Report · For research reference only
Oxalyl chloride → 3-(Bromomethyl)benzoyl chloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Oxalyl chloride | HCID 65578 | — |
| Reactant | 3-(Bromomethyl)benzoic acid | HCID 245650 | — |
| Catalyst | Dimethylformamide | HCID 6228 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 3-(Bromomethyl)benzoyl chloride | HCID 14471076 | — |
Reaction Steps
a solution of 12 g of m-bromomethylbenzoic acid 10.62 g of oxalyl chloride, 100 ml of dichloromethane and 5 drops of dimethylformamide was allowed to stand 48 hours and then evaporated. Hexane and ether were added, the mixture evaporated and the residue distilled on a Kugelroher, giving 12.5 g of m-bromomethylbenzoyl chloride as a yellow liquid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05411983 |
| Source dataset | uspto-grants-1995_05 |
| ORD ID | ord-0166658b1735476e86d6c556d9f08893 |
| Source note | uspto-grants-1995_05 |