Acetyl chloride → HCID 137226513, compound

HRID 35962

Reaction equation

HRID 35962 reaction equation
[Cl:1][C:2](=[N:7][OH:8])[C:3]([Cl:6])=[N:4][OH:5].[C:9](Cl)(=[O:11])[CH3:10].C(N(CC)CC)C>ClC(Cl)C>[C:9]([OH:11])(=[O:5])[CH3:10].[C:9]([OH:11])(=[O:5])[CH3:10].[Cl:1][C:2](=[N:7][OH:8])[C:3]([Cl:6])=[N:4][OH:5]

Participants

5

Reactant 3

HCID 6367Acetyl chlorideHCID 8471TriethylamineHCID 135527345Ethanediimidoyl dichloride, dihydroxy-

Product 1

HCID 137226513HCID 137226513, compoundYield 30%

Reagents, catalysts & solvents 1

HCID 63651,1-DichloroethaneSolvent

Procedure

The mixture of 2.0 g (0.0127 mol) of dichloroglyoxime (Compound No.6), 20 ml of dichloroethane and 2.4 g (0.0306 mol) of acetyl chloride was stirred in an ice bath. To the mixture, triethylamine (3.1 g, 0.0307 mol) was added dropwise, followed by stirring for 30 minutes. The reaction mixture was washed twice with 15 ml of water. The dichloroethane solution was concentrated under reduced pressure, to obtain white crystals of dichloroglyoxime diacetate (Compound No.2, yield: 30%).

Workup

  1. stirringby stirring for 30 minutes
  2. washThe reaction mixture was washed twice with 15 ml of water
  3. concentrationThe dichloroethane solution was concentrated under reduced pressure

Sources & evidence

ORD record
ord-8cf7e900532942bd97b5cb69fa438ac1
Source dataset
uspto-grants-1995_05
Patent number
US05411990

Linked notes

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