(4-Bromobenzylidene)(1-isopropyl-2-methylpropyl)amine → (Benzylidene)(1-isopropyl-2-methylpropyl)amine

HRID 36026

Reaction equation

Br[C:2]1[CH:16]=[CH:15][C:5]([CH:6]=[N:7][CH:8]([CH:12]([CH3:14])[CH3:13])[CH:9]([CH3:11])[CH3:10])=[CH:4][CH:3]=1.C([Li])CCC>>[CH:6](=[N:7][CH:8]([CH:12]([CH3:14])[CH3:13])[CH:9]([CH3:10])[CH3:11])[C:5]1[CH:15]=[CH:16][CH:2]=[CH:3][CH:4]=1

Participants

Reactant 2

HCID 15225580(4-Bromobenzylidene)(1-isopropyl-2-methylpropyl)amine

HCID 178418339Butyllithium

Product 1

HCID 10013317(Benzylidene)(1-isopropyl-2-methylpropyl)amine

Procedure

treating (4-bromobenzylidene)(1-isopropyl-2-methylpropyl)amine with n-butyllithium to give para-lithiated (benzylidene)(1-isopropyl-2-methylpropyl)amine,

Sources & evidence

ORD record: ord-441fefa950c34a06a9cee9e6dabd764b
Source dataset: uspto-grants-1995_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05412102

Linked notes

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