2,2,2-Trifluoroacetophenone → 9-(Trifluoromethyl)phenanthrene-1,10-dicarboxylic Anhydride

HRID 36634

Reaction equation

HRID 36634 reaction equation
[C:1]([O:14]C)(=[O:13])[CH2:2][C:3]1[C:4](=[CH:9][CH:10]=[CH:11][CH:12]=1)[C:5]([O:7]C)=O.[F:16][C:17]([F:27])([F:26])[C:18]([C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1)=O>>[F:16][C:17]([F:27])([F:26])[C:18]1[C:20]2[C:25]([C:12]3[CH:11]=[CH:10][CH:9]=[C:4]4[C:5](=[O:7])[O:14][C:1](=[O:13])[C:2]=1[C:3]=34)=[CH:24][CH:23]=[CH:22][CH:21]=2

Participants

3

Reactant 2

HCID 99052,2,2-TrifluoroacetophenoneHCID 253507Methyl 2-(2-methoxy-2-oxoethyl)benzoate

Product 1

HCID 545139899-(Trifluoromethyl)phenanthrene-1,10-dicarboxylic Anhydride

Procedure

As described in example 14, the following compounds were prepared from dimethyl homophthalate and 2,2,2-trifluoroacetophenone:

Sources & evidence

ORD record
ord-ddd1305d55fc4e8c87dcda14a032cc3a
Source dataset
uspto-grants-1995_05
Patent number
US05416089

Linked notes

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