Methyl 2-(2-methoxy-2-oxoethyl)benzoate → 6-Nitrophenanthrene-1,10-dicarboxylic Anhydride

HRID 36638

Reaction equation

HRID 36638 reaction equation
[C:1]([O:14]C)(=[O:13])[CH2:2][C:3]1[C:4](=[CH:9][CH:10]=[CH:11][CH:12]=1)[C:5]([O:7]C)=O.Br[C:17]1[CH:24]=[C:23]([N+:25]([O-:27])=[O:26])[CH:22]=[CH:21][C:18]=1[CH:19]=O>>[N+:25]([C:23]1[CH:24]=[C:17]2[C:18](=[CH:21][CH:22]=1)[CH:19]=[C:2]1[C:1]([O:14][C:5](=[O:7])[C:4]3[C:3]1=[C:12]2[CH:11]=[CH:10][CH:9]=3)=[O:13])([O-:27])=[O:26]

Participants

3

Reactant 2

HCID 253507Methyl 2-(2-methoxy-2-oxoethyl)benzoateHCID 127210272-Bromo-4-nitrobenzaldehyde

Product 1

HCID 545313486-Nitrophenanthrene-1,10-dicarboxylic Anhydride

Procedure

As described in example 50, the following compounds were prepared from dimethyl homophthalate and 2-bromo-4-nitrobenzaldehyde (Dandegaonker, S. H. J. Ind. Chem. Soc. 1969, 46, 148):

Sources & evidence

ORD record
ord-e5932e09494b4d70b233744645d0ba3f
Source dataset
uspto-grants-1995_05
Patent number
US05416089

Linked notes

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