Dehydrolinalool → Linalool

HRID 366916

Reaction equation

HRID 366916 reaction equation
[CH3:1][C:2]([CH3:11])=[CH:3][CH2:4][CH2:5][C:6]([OH:10])([C:8]#[CH:9])[CH3:7].[H][H]>>[CH2:9]=[CH:8][C:6]([CH2:5][CH2:4][CH:3]=[C:2]([CH3:11])[CH3:1])([CH3:7])[OH:10]

Participants

3

Reactant 2

HCID 62842Dehydrolinalool2×HCID 178418361HCID 178418361, compound

Product 1

HCID 6549Linalool

Procedure

In a 300 ml pressure reactor, 10 g of the Ru catalyst as described in the catalyst production example were placed in a catalyst basket insert and 150 g (0.99 mol) of dehydrolinalool were added. The hydrogenation was carried out using pure hydrogen at a constant pressure of 40 bar and a temperature of 80° C. After a reaction time of 4 hours, the reactor was vented. The conversion of dehydrolinalool was 95% and linalool was obtained in a selectivity of 90%.

Workup

  1. additionwere added
  2. customa temperature of 80° C
  3. customAfter a reaction time of 4 hours

Sources & evidence

ORD record
ord-6e5a1006c86f40c6a0251bc3a7e52998
Source dataset
uspto-grants-2000_10
Patent number
US06130360

Linked notes

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