1-Bromopentadecane → 2-(Heptadecyl)furan

HRID 368370

Reaction equation

[CH2:1]([C:16]1[O:17][CH:18]=[CH:19][CH:20]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15].Br[CH2:22][CH2:23]CCCCCCCCCCCCC>>[CH2:1]([C:16]1[O:17][CH:18]=[CH:19][CH:20]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:22][CH3:23]

Participants

Reactant 2

HCID 123941-Bromopentadecane

HCID 1812502-Pentadecylfuran

Product 1

HCID 1831422-(Heptadecyl)furan

Procedure

2-(heptadecyl)furan (4) was prepared exactly as described above for 2-(pentadecyl)furan, substituting 1-bromo heptadecane for 1-bromopentadecane. The chromatographed product was recrystallized from methanol as described above to afford of 2-(heptadecyl)furan (4) in 48% yield.

Workup

custom2-(heptadecyl)furan (4) was prepared exactly
customThe chromatographed product was recrystallized from methanol

Sources & evidence

ORD record: ord-e98cdf64dc924ad89afde47098b4f488
Source dataset: uspto-grants-2000_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06133313

Linked notes

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