Chlorotrimethylsilane → Silane, trimethyl(trifluoroethenyl)-

Reaction equation

Cl[C:2]([F:6])=[C:3]([F:5])[F:4].C([Li])CCC.Cl[Si:13]([CH3:16])([CH3:15])[CH3:14]>>[F:4][C:3]([F:5])=[C:2]([F:6])[Si:13]([CH3:16])([CH3:15])[CH3:14]

Participants

Reactant 3

HCID 6397Chlorotrimethylsilane

HCID 6594Chlorotrifluoroethylene

HCID 178418339Butyllithium

Product 1

HCID 11205884Silane, trimethyl(trifluoroethenyl)-

Procedure

Chlorotrifluoroethylene of the formula (10) is treated with n-butyl lithium and then reacted with chlorotrimethylsilane of the formula (11) to obtain 1,1,2-trifluoro-2-trimethylsilylethylene of the formula (12). Then, without isolation, this compound (12) is reacted further with a lithium compound of the formula (13) to obtain a difluoroethylene compound of the formula (14).

Sources & evidence

ORD record: ord-d714a4907e85428cb8eae91d6d2f93c7
Source dataset: uspto-grants-1995_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05419851

Reaction notes

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