Ammonia → Triammonium nitridotrisulfate

HRID 371907

Reaction equation

[NH3:1].[S:2](=[O:5])([OH:4])[OH:3].[S:6]([O-:9])([O-:8])=[O:7].[NH4+].[NH4+]>>[NH4+:1].[NH4+:1].[NH4+:1].[N:1]([S:2]([O-:5])(=[O:4])=[O:3])([S:6]([O-:9])(=[O:8])=[O:7])[S:2]([O-:4])(=[O:3])=[O:5]

Participants

Reactant 3

HCID 222Ammonia

HCID 1100Sulfurous Acid

HCID 25041Ammonium Sulfite

Product 1

HCID 20505615Triammonium nitridotrisulfate

Procedure

Diammonium imidobissulfate (NH4SO3)2NH may be prepared by introducing ammonia gas and then sulfurous acid gas into an aqueous solution containing ammonium sulfite to obtain triammonium nitridotrisulfate and heating the obtained nitridotrisulfate in ammonia gas at about 250° C under atmospheric pressure to ammonolyze and then followed by heating at about 300° C.

Sources & evidence

ORD record: ord-fa78363128e1423cbbce8f9c85ee4eb1
Source dataset: uspto-grants-1978_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04088611

Linked notes

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