Peracetic Acid → N-methyl-N-(3,5-dichloro-2-pyridyl)-2-pyridinesulfonamide 1-oxide

Reaction equation

[CH3:1][N:2]([C:12]1[C:17]([Cl:18])=[CH:16][C:15]([Cl:19])=[CH:14][N:13]=1)[S:3]([C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][N:7]=1)(=[O:5])=[O:4].C(OO)(=[O:22])C>>[CH3:1][N:2]([C:12]1[C:17]([Cl:18])=[CH:16][C:15]([Cl:19])=[CH:14][N:13]=1)[S:3]([C:6]1[N+:7]([O-:22])=[CH:8][CH:9]=[CH:10][CH:11]=1)(=[O:5])=[O:4]

Participants

Reactant 2

HCID 6585Peracetic Acid

HCID 20152993N-methyl-N-(3,5-dichloro-2-pyridyl)-2-pyridinesulfonamide

Product 1

HCID 20152989N-methyl-N-(3,5-dichloro-2-pyridyl)-2-pyridinesulfonamide 1-oxide

Procedure

Following the procedures of Example 1, N-methyl-N-(3,5-dichloro-2-pyridyl)-2-pyridinesulfonamide is oxidized with 40% peracetic acid to give the title compound, MS m/e 334.00 (M+).

Sources & evidence

ORD record: ord-6da5e6fc912a4f39abb42807db3359a7
Source dataset: uspto-grants-1988_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04722749

Reaction notes

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