Chlorotrimethylsilane → (3-Iodophenyl)(trimethyl)silane

HRID 375708

Reaction equation

Cl[Si:2]([CH3:5])([CH3:4])[CH3:3].[I:6][C:7]1[CH:12]=[CH:11][CH:10]=[C:9](I)[CH:8]=1>>[I:6][C:7]1[CH:12]=[CH:11][CH:10]=[C:9]([Si:2]([CH3:5])([CH3:4])[CH3:3])[CH:8]=1

Participants

Reactant 2

HCID 6397Chlorotrimethylsilane

HCID 12270Benzene, 1,3-diiodo-

Product 1

HCID 12358196(3-Iodophenyl)(trimethyl)silane

Procedure

1-Iodo-3-trimethylsilanyl-benzene is prepared in a manner analogous to the procedure described in examples 1 and 1a utilizing chlorotrimethylsilane and 1,3-diiodobenzene as the dihalo compound of formula (II).

Sources & evidence

ORD record: ord-2e9a8637cd3445dbb89e2fd508e2d215
Source dataset: uspto-grants-1996_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05486638

Linked notes

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