HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Hexene → Allylhexyldichlorosilane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Hexene | HCID 11597 | — |
| Reactant | Dichloro(prop-2-enyl)silane | HCID 77536 | — |
| Catalyst | Chloroplatinic acid | HCID 61859 | — |
| Solvent | Isopropanol | HCID 3776 | — |
| Product | Allylhexyldichlorosilane | HCID 11218382 | 79,283.797% |
Reaction Steps
Using the same apparatus and procedure described in EXAMPLE 1, 59.7 g (0.71 mol) of 1-hexene and 80 μl of 1% chloroplatinic acid in isopropanol were added to the flask. Through the dropping funnel was added dropwise 10 g (0.07 mmol) of allyldichlorosilane for 30 rain while refluxing. After confirming by gas chromatography to complete the reaction, vacuum distillation (48°-50° C./0.5 torr) gave 12.5 g (79.3%) of 4,4-dichloro-4-sila-1 -decene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05420323 |
| Source dataset | uspto-grants-1995_05 |
| ORD ID | ord-5969ae89b2384cd0b55903e6f6ceefcb |
| Source note | uspto-grants-1995_05 |