Acrylic Acid → Prop-2-enoic acid--prop-2-enal (1/1)

HRID 37736

Reaction equation

HRID 37736 reaction equation
[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3].C(C=C)=O>CO>[CH:1]([CH:2]=[CH2:3])=[O:4].[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3]

Participants

4

Reactant 2

HCID 6581Acrylic Acid2×HCID 7847Acrolein2×

Product 1

HCID 3084492Prop-2-enoic acid--prop-2-enal (1/1)

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Control drug: (acrylic acid:acrolein (mol)=90:10): 7.04 g freshly distilled acrolein and 81.43 g freshly distilled acrylic acid were added into a three-port flask with 530 ml absolute methanol, purged with nitrogen, 5.47 g benzoyl peroxide was added, and the solution was stirred and heated to reflux under nitrogen for 50 h. The reaction solution became a yellowish viscous liquid, which was dried under vacuum at 50-100° C. for 24 hours to form poly (acrolein-acrylic acid) named A5.

Workup

  1. custompurged with nitrogen, 5.47 g benzoyl peroxide
  2. additionwas added
  3. temperatureheated
  4. temperatureto reflux under nitrogen for 50 h
  5. customwas dried under vacuum at 50-100° C. for 24 hours

Sources & evidence

ORD record
ord-6f1d96f9b6954f10a11099f21711a51e
Source dataset
uspto-grants-2013_09
Patent number
US08524216B2

Linked notes

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