HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Hydroxybenzenesulfonic acid → Sodium (3-methylbutoxy)benzenesulfonate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Hydroxybenzenesulfonic acid | HCID 4765 | — |
| Reactant | 1-Iodo-3-methylbutane | HCID 10924 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Isopropanol | HCID 3776 | — |
| Product | Sodium (3-methylbutoxy)benzenesulfonate | HCID 131722889 | — |
Reaction Steps
A solution of 4hydroxybenzenesulfonic acid (10.0 grams, 43.1 mmole) and sodium hydroxide (3.3 grams, 83 mmole) in water (40 mL) was mixed with a solution of 1-iodo-3methylbutane (11.3 mL, 86.4 mmole) in isopropanol (60 mL) and the resulting mixture was heated at reflux for 2 days. The isopropanol was removed by evaporation under vaccuum. The titled compound, 10.0 grams (87%), was collected by filtration washing with isopropanol.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06303636B1 |
| Source dataset | uspto-grants-2001_10 |
| ORD ID | ord-148906a74d08481191dd671d2b696e2d |
| Source note | uspto-grants-2001_10 |