Styrene → GDMA Styrene

HRID 382655

Reaction equation

HRID 382655 reaction equation
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH2:9]([O:16][C:17]([CH2:19][SH:20])=[O:18])[CH2:10][O:11][C:12]([CH2:14][SH:15])=[O:13]>>[CH2:10]([O:11][C:12]([CH2:14][SH:15])=[O:13])[CH2:9][O:16][C:17]([CH2:19][SH:20])=[O:18].[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

Participants

3

Reactant 2

HCID 7501Styrene2×HCID 61059Ethylene di(S-thioacetate)

Product 1

HCID 131721770GDMA Styrene

Procedure

Styrene (481.4 g, 4.62 eq.) was weighed into a 2000 ml, three neck, round bottom flask along with TPO (1.52 g). The flask was sealed with rubber stoppers and placed in a 60° C. oven for approximately 20 minutes. The contents were swirled occasionally until the TPO dissolved into the styrene. The flask was removed from the oven and allowed to cool to less than 40° C. at which point GDMA (518.6 g, 4.467 eq.) was weighed into the flask.

Workup

  1. customThe flask was sealed with rubber stoppers
  2. customplaced in a 60° C.
  3. customfor approximately 20 minutes
  4. customThe flask was removed from the oven

Sources & evidence

ORD record
ord-518ed148ec3b4428a40b53509f42f34c
Source dataset
uspto-grants-2001_10
Patent number
US06310161B1

Linked notes

Loading…