HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethanol → HCID 178481214, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | Oxonium, trimethyl-, tetrafluoroborate(1-) (1:1) | HCID 2735153 | — |
| Reactant | 1-(4'-Phenylsulfonylphenyl)benzimidazole | HCID 66879359 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 178481214 | HCID 178481214 | 80% |
Reaction Steps
A solution of 1-(4′-phenylsulfonylphenyl)benzimidazole (6.7 g, 20 mmol) in dichloromethane (100 ml) is admixed at −10° C. with trimethyloxonium tetrafluoroborate (3.3 g, 22 mmol) and stirred under argon for 16 h. After adding ethanol, the precipitate formed is filtered off and washed with cold petroleum ether. Yield: 80%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08384068B2 |
| Source dataset | uspto-grants-2013_02 |
| ORD ID | ord-125cf9e9a4814785bc5c14cd4c395ecc |
| Source note | uspto-grants-2013_02 |