Nitric Acid → Benzenamine, 4-(1-naphthalenyl)-

HRID 393504

Reaction equation

HRID 393504 reaction equation
[C:1]1([C:7]2[C:16]3[C:11](=[CH:12][CH:13]=[CH:14][CH:15]=3)[CH:10]=[CH:9][CH:8]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[N+:17]([O-])(O)=O>C(O)(=O)C>[NH2:17][C:4]1[CH:5]=[CH:6][C:1]([C:7]2[C:16]3[C:11](=[CH:12][CH:13]=[CH:14][CH:15]=3)[CH:10]=[CH:9][CH:8]=2)=[CH:2][CH:3]=1

Participants

4

Reactant 2

HCID 944Nitric AcidHCID 117951-Phenylnaphthalene

Product 1

HCID 2760169Benzenamine, 4-(1-naphthalenyl)-Yield 39%

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

204 g of 1-phenylnaphthalene was nitrated in 1 l of acetic acid using nitric acid. The product was reduced using a reduced iron to obtain 1-(4-aminophenyl)naphthalene (yield: 39%).

Sources & evidence

ORD record
ord-92114018ac41458aa5c149127b0029f4
Source dataset
uspto-grants-2004_10
Patent number
US06808869B1

Linked notes

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