HuagongsheHuagongshe Chemistry Print Report · For research reference only
Monoepoxycyclododecadiene → Cyclododecanol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Monoepoxycyclododecadiene | HCID 54352584 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Product | Cyclododecanol | HCID 15595 | 20% |
Reaction Steps
In a reaction example shown in this report, when epoxycyclododecadiene is subjected to a reduction reaction with a hydrogen gas in the presence of a palladium catalyst carried on γ-alumina under a reduced pressure of 1.3 MPa at a reaction temperature of 90° C., cyclododecanol is obtained at a yield of 20%. In the report, a palladium catalyst carried on titania and a palladium catalyst carried on silica were employed. In each case, the yield of the cyclododecanol was less than 20%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06608235B1 |
| Source dataset | uspto-grants-2003_08 |
| ORD ID | ord-d0480ba8cfda4206b9d3c84575546c15 |
| Source note | uspto-grants-2003_08 |