HuagongsheHuagongshe Chemistry Print Report · For research reference only
2,2'-Dimethyl-5,5'-bis(3-bromo-1-adamantyl)biphenyl → 2,2'-Dimethyl-5,5'-bis(3-(3,5-diethynylphenyl)-1-adamantyl)biphenyl
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2,2'-Dimethyl-5,5'-bis(3-bromo-1-adamantyl)biphenyl | HCID 67524109 | — |
| Reactant | 2,2'-Dimethyl-5,5'-bis(1-adamantyl)biphenyl | HCID 86641950 | — |
| Product | 2,2'-Dimethyl-5,5'-bis(3-(3,5-diethynylphenyl)-1-adamantyl)biphenyl | HCID 86641951 | 73.5% |
Reaction Steps
From the obtained 2,2′-dimethyl-5,5′-bis(1-adamantyl)-biphenyl 10 g, the same method as in Synthesis Example 7 was used to synthesize 2,2′-dimethyl-5,5′-bis(3-bromo-1-adamantyl)biphenyl 4.5 g, then the same method as in Synthesis Example 3 was used to obtain 2,2′-dimethyl-5,5′-bis(3-(3,5-diethynylphenyl)-1-adamantyl)biphenyl 3.8 g.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08530596B2 |
| Source dataset | uspto-grants-2013_09 |
| ORD ID | ord-8af8d5cfae954018b9b767f588c5e2c4 |
| Source note | uspto-grants-2013_09 |