HCID 54549583, compound → HCID 10107954, compound
Reaction equation
[C:1]([O:5][C:6]([C:8]1[S:9][C:10]([CH:13]=[CH:14][C:15]([O:17][CH2:18][CH3:19])=[O:16])=[CH:11][CH:12]=1)=[O:7])([CH3:4])([CH3:3])[CH3:2].[H][H]>C(O)C.[Pd]>[C:1]([O:5][C:6]([C:8]1[S:9][C:10]([CH2:13][CH2:14][C:15]([O:17][CH2:18][CH3:19])=[O:16])=[CH:11][CH:12]=1)=[O:7])([CH3:4])([CH3:3])[CH3:2]Participants
5
Reactant 2
Product 1
Reagents, catalysts & solvents 2
Procedure
0.846 g (3 mmol) of the product obtained in step d) were dissolved in 100 ml of dry ethanol. 150 mg of 10% palladium on charcoal were added, and the suspension was hydrogenated at 50° C. and 4 bar hydrogen pressure. After filtration the solvent was removed in vacuo. 0.6 g of a colourless oil were obtained.
Workup
- customwas hydrogenated at 50° C.
- filtrationAfter filtration the solvent
- customwas removed in vacuo
Sources & evidence
- ORD record
- ord-1fabac8cbe7342049b685c8d6b070e47
- Source dataset
- uspto-grants-2003_05
- Patent number
- US06566366B1
Reaction notes
Loading…