(+)-Solketal → HCID 73416232, compound

HRID 414949

Reaction equation

CC1(C)O[C@@H](CO)CO1.CC(C)(C)[Si](C1C=CC=CC=1)(C1C=CC=CC=1)OC[C@@H](O)CO.[N+:33]([O:36][C@@H:37]([CH2:40][O:41][N+:42]([O-:44])=[O:43])[CH2:38][OH:39])([O-:35])=[O:34]>>[N+:33]([O:36][C@H:37]([CH2:40][O:41][N+:42]([O-:44])=[O:43])[CH2:38][OH:39])([O-:35])=[O:34]

Participants

Reactant 3

HCID 736057(+)-Solketal

HCID 10806357(2S)-3-(2,2-Dimethyl-1,1-diphenyl-1-silapropoxy)propane-1,2-diol

HCID 73416231HCID 73416231, compound

Product 1

HCID 73416232HCID 73416232, compound

Procedure

The title compound was prepared in four steps from ((4S)-2,2-dimethyl-1,3-dioxolan-4-yl)methan-1-ol following the procedures for Examples 5a, 5b, 5c, and 5d.

Sources & evidence

ORD record: ord-5726486e476e461186a9115a3428c48b
Source dataset: uspto-grants-2012_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08088762B2

Linked notes

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