P-Anisidine → N-(4-methoxyphenyl)-2,4-dinitrobenzamide

HRID 427638

Reaction equation

[CH3:1][O:2][C:3]1[CH:9]=[CH:8][C:6]([NH2:7])=[CH:5][CH:4]=1.[N+:10]([C:13]1[CH:21]=[C:20]([N+:22]([O-:24])=[O:23])[CH:19]=[CH:18][C:14]=1[C:15](Cl)=[O:16])([O-:12])=[O:11]>>[CH3:1][O:2][C:3]1[CH:9]=[CH:8][C:6]([NH:7][C:15](=[O:16])[C:14]2[CH:18]=[CH:19][C:20]([N+:22]([O-:24])=[O:23])=[CH:21][C:13]=2[N+:10]([O-:12])=[O:11])=[CH:5][CH:4]=1

Participants

Reactant 2

HCID 7732P-Anisidine

HCID 884012,4-Dinitrobenzoyl chloride

Product 1

HCID 3343664N-(4-methoxyphenyl)-2,4-dinitrobenzamideYield 74.1%

Procedure

Using the procedure described in Example 93, Part A, 4-methoxyaniline (43.76 mmol) and 2,4-dinitrobenzoyl chloride (48.14 mmol) yielded 10.29 g (74%) of the title compound.

Sources & evidence

ORD record: ord-835b17561d724ece938ba9a327e8d24f
Source dataset: uspto-grants-2001_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06313122B1

Linked notes

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