HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,2-Benzenedicarboxylic acid, 4-nitro- → N-Hydroxy-4-nitrophthalimide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,2-Benzenedicarboxylic acid, 4-nitro- | HCID 69121 | — |
| Reactant | Hydroxylammonium phosphate (3:1) | HCID 10176537 | — |
| Product | N-Hydroxy-4-nitrophthalimide | HCID 11458432 | — |
Reaction Steps
Analogous to Example 4, but from 500 mg (2.37 mmol) of 4-nitrophthalic acid (tech., contaminated with approximately 10% of 3-nitrophthalic acid) and 187 mg (0.974 mmol) of hydroxylammonium phosphate at a bath temperature of 130° C. The yield was 332 mg (67%, approximately 5% contaminated).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06316639B1 |
| Source dataset | uspto-grants-2001_11 |
| ORD ID | ord-5f980e1714e949f3a1ec2a42ce0bead9 |
| Source note | uspto-grants-2001_11 |